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Ultrasmooth metallic foils for growth of high quality graphene by chemical vapor deposition

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PROCHÁZKA Pavel MACH Jindřich BISCHOFF Dominik LIŠKOVÁ Zuzana DVOŘÁK Petr VAŇATKA Marek SIMONET Pauline VARLET Anastasia HEMZAL Dušan PETRENEC Martin KALINA Lukáš BARTOŠÍK Miroslav ENSSLIN Klaus VARGA Peter ČECHAL Jan ŠIKOLA Tomáš

Rok publikování 2014
Druh Článek v odborném periodiku
Časopis / Zdroj NANOTECHNOLOGY
Fakulta / Pracoviště MU

Středoevropský technologický institut

Citace
www http://iopscience.iop.org/0957-4484/25/18/185601/article
Doi http://dx.doi.org/10.1088/0957-4484/25/18/185601
Obor Fyzika pevných látek a magnetismus
Klíčová slova graphene; CVD growth; metallic foils
Popis Synthesis of graphene by chemical vapor deposition is a promising route for manufacturing large-scale high-quality graphene for electronic applications. The quality of the employed substrates plays a crucial role, since the surface roughness and defects alter the graphene growth and cause dif fi culties in the subsequent graphene transfer. Here, we report on ultrasmooth high- purity copper foils prepared by sputter deposition of Cu thin fi lm on a SiO 2 /Si template, and the subsequent peeling off of the metallic layer from the template. The surface displays a low level of oxidation and contamination, and the roughness of the foil surface is generally de fi ned by the template, and was below 0.6 nm even on a large scale. The roughness and grain size increase occurred during both the annealing of the foils, and catalytic growth of graphene from methane ( +- 1000 °C), but on the large scale still remained far below the roughness typical for commercial foils. The micro-Raman spectroscopy and transport measurements proved the high quality of graphene grown on such foils, and the room temperature mobility of the graphene grown on the template stripped foil was three times higher compared to that of one grown on the commercial copper foil. The presented high-quality copper foils are expected to provide large-area substrates suitable for electronic applications.
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