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Adsorption of silver nanoparticles from aqueous solution on copper based metal organic frameworks (HKUST-1)

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CONDE-GONZALEZ J.E. PEŇA MENDÉZ Eladia Maria RYBÁKOVÁ Stanislava PASAN S. RUIZ-PEREZ J. HAVEL Josef

Rok publikování 2016
Druh Článek v odborném periodiku
Časopis / Zdroj Chemosphere
Fakulta / Pracoviště MU

Přírodovědecká fakulta

Citace
Doi http://dx.doi.org/10.1016/j.chemosphere.2016.02.005
Obor Ekologie - společenstva
Klíčová slova Metal organic frameworks; Silver nanoparticles; Chlorides; Water
Popis Silver nanoparticles (AgNP) are emerging pollutants. The use of novel materials such as Cu-(benzene 1,3,5-tricarboxylate, BTC) Metal-Organic Framework (MOFs), for AgNP adsorption and their removal from aqueous solutions has been studied. The effect of different parameters was followed and isotherm model was suggested. MOFs adsorbed fast and efficiently AgNP in the range C-0 < 10 mg L-1, being Freundlich isotherm (R = 0.993) these data fitted to. Among studied parameters a remarkable effect of chloride on sorption was found, thus their possible interactions were considered. The high adsorption efficiency of AgNP was achieved and it was found to be very fast. The feasibility of adsorption on Cu-(BTC) was proved in spiked waters. The results showed the potential interest of new material as adsorbent for removing AgNP from environment. (C) 2016 Elsevier Ltd. All rights reserved.

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