Informace o publikaci

Efficient synthesis of ether phosphonates using trichloroacetimidate and acetate coupling methods

Autoři

FATHALLA Walid Mohamed ALI Ibrahim PAZDERA Pavel

Rok publikování 2018
Druh Článek v odborném periodiku
Časopis / Zdroj RSC ADVANCES
Fakulta / Pracoviště MU

Přírodovědecká fakulta

Citace
www http://dx.doi.org/10.1039/c8ra00702k
Doi http://dx.doi.org/10.1039/c8ra00702k
Klíčová slova ALPHA-HYDROXYPHOSPHONATES; ACTIVATION; ARYL
Popis A series of ether phosphonates have been prepared by trichloroacetimidate and acetate coupling methods. Trichloroacetimidates or acetates were treated with primary and secondary alcohols as O-nucleophiles in the presence of catalytic TMSOTf to afford 21 examples of diethyl alkyloxy(substitutedphenyl)methyl phosphonates via C-O bond formation in 55-90% yields and short reaction time.

Používáte starou verzi internetového prohlížeče. Doporučujeme aktualizovat Váš prohlížeč na nejnovější verzi.

Další info