Informace o publikaci
Bis(difluorooxoiodonium)Selenate.
| Autoři | |
|---|---|
| Rok publikování | 1997 |
| Druh | Článek ve sborníku |
| Konference | 17th European Crystallographic Meeting. Book of Abstracts. |
| Fakulta / Pracoviště MU | |
| Citace | |
| Obor | Anorganická chemie |
| Klíčová slova | Bis(difluorooxoiodonium)Selenate; Synthesis; Crystal structure |
| Popis | Bis(difluorooxoiodonium)Selenate.The title compound has been prepared by reaction of iodine pentafluoride with (SeO3)4. Its X-ray single crystal structure analysis revealed a rather covalent than ionic structure with an F2(O)IOSeO2OI(O)F2 molecule. Due to unsaturated coordination of I(V) atoms, every molecule is linked via 4 relatively strong SeO...I interactions to its two nearest neighbours forming corrugated eight-membered rings. These rings are joined by common Se(VI) spiroatoms into infinite chains. |
| Související projekty: |