Publication details

Diethyl [4-(2,2:6,2-terpyridine-4-yl)phenyl]phosphonate

Authors

CHYBA Jan NEČAS Marek PINKAS Jiří

Year of publication 2013
Type Article in Periodical
Magazine / Source Acta Crystallographica Section E: Structure Reports Online
MU Faculty or unit

Central European Institute of Technology

Citation
Web http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3885073/
Doi http://dx.doi.org/10.1107/S1600536813031541
Field Inorganic chemistry
Keywords terpyridine; phosphonate; structure
Description The title compound, C25H24N3O3P, was obtained by catalytic phosphonation of 4'-(4-bromphenyl)-2,2':6',2''-terpyridine. The terpyridine moiety is nearly planar, the dihedral angles between the central and the outer rings being 4.06 (9) and 5.39 (9) deg. The N atoms in the two pyridine rings are oriented nearly antiperiplanar to that of the central ring. The benzene ring is rotated out of the plane of the central ring of the terpyridine unit by 34.65 (6) deg.
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