Publication details

Successful oxidation of Ph2P(CH2)nPPh2 (n = 2, 4, 6) by tellurium leading to Ph2P(Te)(CH2)nP(Te)Ph2

Authors

JEREMIAS Lukáš BABIAK Michal KUBÁT Václav CALHORDA Maria J. TRÁVNÍČEK Zdeněk NOVOSAD Josef

Year of publication 2014
Type Article in Periodical
Magazine / Source RSC Advances
MU Faculty or unit

Faculty of Science

Citation
Doi http://dx.doi.org/10.1039/c4ra00157e
Field Inorganic chemistry
Keywords bisdiphenylphosphinoalkanes tellurium X-ray diffraction
Attached files
Description The first successful syntheses of Ph2P(Te)(CH2)nP(Te)Ph2 (n = 2, 4, 6) via oxidation of Ph2P(CH2)nPPh2 by tellurium powder are reported. The prepared compounds were characterized by elemental analysis, 31P and 125Te NMR spectroscopy, and single-crystal X-ray analysis.

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