Publication details

Synthesis of Tin (IV) Heteroarylalkenols and Their Susceptibility Towards Fluorination

Authors

PODHORSKÝ Ján MORAVEC Zdeněk PINKAS Jiří HEGEMANN Corrina MATHUR Sanjay

Year of publication 2016
Type Conference abstract
MU Faculty or unit

Faculty of Science

Citation
Description In our work, we focused on reactions of organometallic tin (IV) precursors, such as Sn(OtBu)4, Me3SnCl, and Me3SnF, with ß-heteroarylalketonates: 3,3,3-tri?uoro(pyridin-2-yl)propen-2-ol, 3,3,3-tri?uoro(dimethyl-1,3-oxazol-2-yl)propen-2-ol, and 3,3,3-tri?uoro(1,3-benzthiazol-2- yl)propen-2-ol. Obtained compounds were exposed to various fluorination agents (HF, XeF2, and NH4F) and their reactivity towards them was compared to already published Sn (II) ß-heteroarylalketonates, in order to determine their suitability as possible FTO precursors.

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