Publication details

Retrospective analysis of "new" flame retardants in the global atmosphere under the GAPS Network

Authors

LEE Sum Chi SVERKO Ed HARNER Tom POZO Karla Andrea BARRESI Enzo SCHACHTSCHNEIDER JoAnne ZARUK Donna DEJONG Maryl NARAYAN Julie

Year of publication 2016
Type Article in Periodical
Magazine / Source Environmental Pollution
MU Faculty or unit

Faculty of Science

Citation
Web http://www.sciencedirect.com/science/article/pii/S026974911630080X
Doi http://dx.doi.org/10.1016/j.envpol.2016.01.080
Field Environment influence on health
Keywords Non-PBDE flame retardants; Passive air sampling; PUF disk; GAPS Network; HBCD
Description A retrospective analysis was conducted on air samples that were collected in 2005 under the Global Atmospheric Passive Sampling (GAPS) Network around the time period when the Stockholm Convention on Persistent Organic Pollutants came into force. Results are presented for several new flame retardants, including hexabromocyclododecane (HBCD), which was recently listed under the Convention (2013). These results represent the first global-scale distributions in air for these compounds. The targeted compounds are shown to have unique global distributions in air, which highlights, the challenges in understanding the sources and environmental fate of each chemical, and ultimately in their assessments as persistent organic pollutants. The study also demonstrates the feasibility of using the PUF disk passive Air Sampler to study these new flame retardants in air, many of which exist entirely in the particle-phase as demonstrated in this study using a K-OA-based partitioning model.

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