Publication details

Assessing Air-Surface Exchange and Fate of Mercury in a Subtropical Forest Using a Novel Passive Exchange-Meter Device

Authors

ZHANG Hui NIZZETTO Luca FENG Xinbin BORGA Katrine SOMMAR Jonas FU Xuewu ZHANG Hua ZHANG Gan LARSSEN Thorjorn

Year of publication 2019
Type Article in Periodical
Magazine / Source ENVIRONMENTAL SCIENCE & TECHNOLOGY
MU Faculty or unit

Faculty of Science

Citation
Web Full Text
Doi http://dx.doi.org/10.1021/acs.est.8b06343
Keywords ATMOSPHERIC MERCURY; LITTER DECOMPOSITION; ELEMENTAL MERCURY; SPATIAL-PATTERNS; GASEOUS MERCURY; ORGANIC-MATTER; STREAM WATER; SOIL; DEPOSITION; EMISSIONS
Description A novel passive exchange meter (EM) device was developed to assess air-surface exchange and leaching of Hg in a forest floor. Flux measurements were carried out in a subtropical forest ecosystem during a full year. Over 40% of the Hg fixed in fresh forest litter was remobilized in less than 60 days in warm and humid conditions as a response to rapid turnover of labile organic matter (OM). A two-block experiment including understory and clearing showed that losses of Hg covaried with seasonal conditions and was significantly affected by forest coverage. The process controlling the bulk loss of total Hg from the litter was volatilization, which typically represented 76-96% of the loss processes (F-loss). The F-loss ranges were 520-1370 and 165-942 ng m(-2) d(-1) in the understory and clearing, respectively. On a yearly basis, deposition of airborne Hg exceeded total losses by a factor of 2.5 in the clearing and 1.5 in the understory. The vegetation litter in this subtropical forest therefore represented a net sink of atmospheric Hg. This study provided a novel approach to Hg air-soil exchange measurements and further insights on the link between Hg remobilization and OM turnover along with its environmental drivers.

You are running an old browser version. We recommend updating your browser to its latest version.

More info