Publication details

Sintering of inkjet-printed silver nanoparticles by large-area atmospheric pressure nitrogen plasma

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Authors

VIDA Július SOLAK Selen SHAO Yuhang HOMOLA Tomáš LIST-KRATOCHVIL Emil HERMERSCHMIDT Felix

Year of publication 2025
Type Article in Periodical
Magazine / Source Applied Physics A
MU Faculty or unit

Faculty of Science

Citation
web https://doi.org/10.1007/s00339-024-08206-y
Doi http://dx.doi.org/10.1007/s00339-024-08206-y
Keywords Plasma sintering; Inkjet printing; Silver nanoparticles; Low-temperature sintering; DCSBD
Description Silver nanoparticles were sintered at atmospheric pressure using nitrogen plasma generated by diffuse coplanar surface barrier discharge (DCSBD). Compared to the standard thermal sintering of 1 h at 140 degrees C only 8 min of nonthermal plasma treatment at 50 degrees C were necessary to sufficiently anneal the silver nanoparticle film. Electrical resistivity as low as 9 x 10-6 Omega cm was achieved, i.e., 17% of the bulk conductivity of silver. X-ray photoelectron spectroscopy was used to study the removal of organic moieties from the surface of the inkjet-printed layers. Scanning electron microscopy revealed in detail the process of formation of interconnection between nanoparticles. Our findings pave the way for implementing low-cost and eco-friendly DCSBD plasma sintering into continuous roll-to-roll processing in the future for the annealing of silver nanoparticles on substrates that cannot tolerate high temperatures.
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