Informace o publikaci
Does an analysis of polychlorinated biphenyl (PCB) distribution in mountain soils across China reveal a latitudinal fractionation paradox?
| Autoři | |
|---|---|
| Rok publikování | 2014 |
| Druh | Článek v odborném periodiku |
| Časopis / Zdroj | Environmental Pollution |
| Fakulta / Pracoviště MU | |
| Citace | |
| www | http://www.sciencedirect.com/science/article/pii/S0269749114003601 |
| Doi | http://dx.doi.org/10.1016/j.envpol.2014.08.021 |
| Obor | Kontaminace a dekontaminace půdy včetně pesticidů |
| Klíčová slova | POP; PCB; Fractionation; Cold trapping; Mountain; Soil; Latitude; Forest |
| Popis | Organic and mineral soil horizons from forests in 30 mountains across China were analysed for polychlorinated biphenyl (PCB). Soil total organic carbon (TOC) content was a key determinant of PCB distribution explaining over 90% of the differences between organic and mineral soils, and between 30% and 60% of the variance along altitudinal and regional transects. The residual variance (after normalization by TOC) was small. Tri- to tetra-CB levels were higher in the South in relation to high source density and precipitation. Heavier congeners were instead more abundant at mid/high-latitudes where the advection pattern was mainly from long range transport. This resulted in a latitudinal fractionation opposite to theoretical expectations. The study showed that exposure to sources with different characteristics, and possibly accumulation/degradation trends of different congeners in soils being out-of-phase at different latitudes, can lead to an unsteady large scale distribution scenario conflicting with the thermodynamic equilibrium perception. (C) 2014 Elsevier Ltd. All rights reserved. |
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