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Post-magmatic hydrothermal mineralization associated with Cretaceous picrite (Outer Western Carpathians, Czech Republic): interaction between host rock and externally derived fluid.

Název česky Postmagmatická hydrotermální mineralizace pikritické horniny křídového stáří (Vnější Západní Karpaty, Česká republika): interakce mezi hostitelskou horninou a externě derivovanými fluidy.
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DOLNÍČEK Zdeněk URUBEK Tomáš KROPÁČ Kamil

Rok publikování 2015
Druh Článek v odborném periodiku
Časopis / Zdroj Geologica Carpathica
Fakulta / Pracoviště MU

Přírodovědecká fakulta

Citace
www http://www.geologicacarpathica.com/GeolCarp_Vol61_No4_327_339.html
Doi http://dx.doi.org/10.2478/v10096-010-0019-y
Obor Geologie a mineralogie
Klíčová slova Outer Western Carpathians, stable isotopes, strontium isotopes, fluid-rock interaction, veins, fluid inclusions, amygdules, REE, picrite.
Popis Mineralogy, fluid inclusions, C, O, S, Sr isotopes and trace elements have been studied in amygdule and vein mineralization hosted by the Lower Cretaceous effusive picrite at Hončova hůrka (Silesian Unit, Flysch Belt of the Outer Western Carpathians). Besides dominating dolomite, magnesite, siderite, quartz, calcite, chlorite, glauconite, fluorite, barite, pyrite and millerite were also identified. The parent fluids are characterized by low temperatures (< 50—170 °C), low salinities (0.4 to 3.7 wt. % NaCl eq.), low content of strong REE-complexing ligands, ?18O, ?13C and ?34S ranges of 0/+ 14 ‰ SMOW, 0/—9 ‰ PDB and ~0 ‰ CDT, respectively, and initial 87Sr/86Sr ratios much more radiogenic (0.7060 to 0.7068) than those of host picrite (0.7042 and 0.7046). The fluids are interpreted to be predominantly of external origin, derived from mixing of seawater with diagenetic waters produced by dewatering of clay minerals in the associated flysch sediments. The isotope and REE signatures indicate interaction of at least a part of fluids with sedimentary carbonates. The interaction of fluids with host picrite led to strong alteration of rock-forming minerals and leaching of some elements (Mg, Ni, S, partly also REE) that widely participated during precipitation of vein- and amygdule-hosted mineral phases.

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