Informace o publikaci
Efficient synthesis of ether phosphonates using trichloroacetimidate and acetate coupling methods
| Autoři | |
|---|---|
| Rok publikování | 2018 |
| Druh | Článek v odborném periodiku |
| Časopis / Zdroj | RSC ADVANCES |
| Fakulta / Pracoviště MU | |
| Citace | |
| Doi | http://dx.doi.org/10.1039/c8ra00702k |
| Klíčová slova | ALPHA-HYDROXYPHOSPHONATES; ACTIVATION; ARYL |
| Popis | A series of ether phosphonates have been prepared by trichloroacetimidate and acetate coupling methods. Trichloroacetimidates or acetates were treated with primary and secondary alcohols as O-nucleophiles in the presence of catalytic TMSOTf to afford 21 examples of diethyl alkyloxy(substitutedphenyl)methyl phosphonates via C-O bond formation in 55-90% yields and short reaction time. |