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Comparability of long-term temporal trends of POPs from co-located active and passive air monitoring networks in Europe

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KALINA Jiří WHITE Kevin Bradley SCHERINGER Martin PŘIBYLOVÁ Petra KUKUČKA Petr AUDY Ondřej KLÁNOVÁ Jana

Rok publikování 2019
Druh Článek v odborném periodiku
Časopis / Zdroj ENVIRONMENTAL SCIENCE-PROCESSES & IMPACTS
Fakulta / Pracoviště MU

Přírodovědecká fakulta

Citace
www http://dx.doi.org/10.1039/c9em00136k
Doi http://dx.doi.org/10.1039/c9em00136k
Klíčová slova PERSISTENT ORGANIC POLLUTANTS; POLYCHLORINATED-BIPHENYLS; POTENTIAL SOURCES; SEASONAL TRENDS; AMBIENT AIR; SAMPLERS; PCBS; ATMOSPHERE; CALIBRATION; PBDES
Popis The comparability of data from active (ACT) and passive sampling (PAS) of persistent organic pollutants (POPs) in air is hindered by uncertainties related to the derivation of sampling rates and concentrations, as well as differences in the duration, volume and frequency of sampling. Although data from ACT have been used extensively in short-term PAS calibration studies, no attempts have been made to evaluate the comparability of long-term trends calculated from PAS to established ACT trends. This is crucial, as continuous long-term ACT is unfeasible in most regions of the world. To address these challenges, we calculated and compared trends for organochlorine pesticides (OCPs), polychlorinated biphenyls (PCBs) and polybrominated diphenyl ethers (PBDEs) at the six sites in Europe with at least 5 years of co-located ACT and PAS data (2012-2016): Birkenes, Kosetice, Pallas, Rao, Storhofoi and Zeppelin. Strong agreement of ACT and PAS trends was observed for most OCPs and PCBs. Apart from two PCBs at Storhofoi, all pairs of ACT and PAS trends followed the same direction. However, differences in the magnitude, significance and confidence intervals of their slopes were observed for some compounds and were primarily attributed to the short duration of the PAS time series. Despite some limitations, our results suggest that the comparability of ACT and PAS POP trends will continue to improve with additional years of data. This study confirms the suitability of PAS for the calculation of long-term POP trends in air, and highlights the importance of continuous sampling at established monitoring sites with consistent analytical methods.
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