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Microwave-assisted synthesis of platelet-like cobalt metal-organic framework, its transformation to porous layered cobalt-carbon nanocomposite discs and their utilization as anode materials in sodium-ion batteries

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SKODA David KAZDA Tomas MUNSTER Lukas HANULIKOVA Barbora STYSKALIK Ales ELOY Pierre DEBECKER Damien P. VILCAKOVA Jarmila CECH Ondrej ŠIMONÍKOVÁ Lucie KANICKÝ Viktor KURITKA Ivo

Rok publikování 2020
Druh Článek v odborném periodiku
Časopis / Zdroj Journal of Energy Storage
Fakulta / Pracoviště MU

Přírodovědecká fakulta

Citace
www https://www.sciencedirect.com/science/article/pii/S2352152X19310783?via%3Dihub
Doi http://dx.doi.org/10.1016/j.est.2019.101113
Klíčová slova HIGH-PERFORMANCE ANODES; COORDINATION POLYMERS; ENERGY-STORAGE; HIGH-CAPACITY; LITHIUM; NANOPARTICLES; EFFICIENT; NANOSTRUCTURES; SPECTROSCOPY; ADSORPTION
Popis In this work a facile microwave-assisted synthesis of a platelet-like cobalt-based metal-organic framework (MOF) material is presented. This material was synthesized from cobalt(II) acetylacetonate and biphenyl-4,4'-dicarboxylic acid (Bpdc) in N,N'-dimethylformamide at 160 degrees C. As-prepared Co-Bpdc MOF product with a platelet-like disc architecture was transformed by heat treatment in a nitrogen atmosphere at 800 degrees C to porous cobalt-carbon nanocomposite discs. It is demonstrated that this synthetic strategy allows for obtaining magnetic microporous carbon layered discs with homogeneously incorporated metallic cobalt nanoparticles with a size of ca. 4 nm. The Co-C nanocomposite material was characterized by a variety of physico-chemical methods. It is shown that both Co-Bpdc MOF and Co-C nanocomposite were electrochemically active in sodium battery system as a material for the negative electrode. The high capacity retention over 80% and capacities over 200 mAh g(-1) in the sodium-ion battery systems have been achieved.

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