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Water oxidation electrocatalyst: A new application area for Ruthner powder waste material

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GHORBANZADEH Soghra HOSSEINI Seyyed Alireza TAGHDIRI Amin ALISHAHI Mostafa

Rok publikování 2022
Druh Článek v odborném periodiku
Časopis / Zdroj Boletin de la Sociedad Espanola de Ceramica y Vidrio
Fakulta / Pracoviště MU

Přírodovědecká fakulta

Citace
www https://www.sciencedirect.com/science/article/pii/S0366317521000029
Doi http://dx.doi.org/10.1016/j.bsecv.2021.01.002
Klíčová slova Water splitting; Oxygen evolution reaction; Electrophoretic deposition; Ruthner powder
Popis Ruthner powder is a by-product of the steel hot-rolling process. This study introduces a new application area for this waste material by investigating its activity for the oxygen evolution reaction. Ruthner powder with the ot-Fe(2)O(3 )phase structure was deposited on the carbon paper substrates using the electrophoretic deposition (EPD) process to fabricate the electrodes. The effect of the concentration of cetrimonium bromide ([CTAB]) and the Ruthner powder ([RP]) in the EPD cell on the morphology and activity of the electrodes were investigated by SEM, LSV, and EIS techniques. The results revealed the formation of a homogenous layer on the carbon paper when [CTAB] and [RP] were respectively 0.4 g.l(-1) and 0.2 g.l(-1). The obtained electrode showed the best activity among all fabricated electrodes. In particular, its onset overpotential and overpotential at a current density of 10 mA.cm(-2) were respectively 85% and 25% lower than those of bare carbon electrodes.

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