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Electrospun PAN Membrane Loaded with AgInP2Se6 Nanosheets for Triboelectric Energy Harvesting

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OLIVEIRA Filipa M. STURALA Jiri WU Bing ALRABIE Latifah KUNDRÁT Vojtěch ZALESAK Jakub NEVES Ana I. S. CRACIUN Monica F. GUSMAO Rui SOFER Zdenek KOVALSKA Evgeniya

Rok publikování 2026
Druh Článek v odborném periodiku
Časopis / Zdroj SMALL
Fakulta / Pracoviště MU

Přírodovědecká fakulta

Citace
www https://onlinelibrary.wiley.com/doi/epdf/10.1002/smll.202511763?src=getftr&utm_source=clarivate&getft_integrator=clarivate
Doi https://doi.org/10.1002/smll.202511763
Klíčová slova 2D materials; electrospinning; energy harvesting; liquid-phase exfoliation; metal phosphorous trichalcogenide; polymer composite; triboelectric nanogenerators
Přiložené soubory
Popis To address the gap in the application of mixed-metal phosphorus trichalcogenides (MIMIIIP2X6) in energy harvesting systems, this work investigates the incorporation of exfoliated silver-indium-phosphorus-selenide (AgInP2Se6) into electrospun polyacrylonitrile (PAN) fibers for triboelectric nanogenerator (TENG) applications. This research marks the first-time exfoliation of AgInP2Se6 (exf-AgInP2Se6) and its integration into a polymer matrix, resulting in the first demonstration of a MIMIIIP2X6-based polymer composite processed into a flexible nanogenerator via electrospinning. Comprehensive structural and morphological characterization confirms the successful incorporation of exfoliated AgInP2Se6 within the PAN fiber without compromising the crystallinity or fiber integrity. The exf-AgInP2Se6/PAN membrane is tested as a TENG device, operating in contact-separation mode, and demonstrates excellent output performance and stability under mechanical deformation. The device exhibits competitive electrical performance, reaching a peak power density of 480 mWm-2 at 1 G Omega load, and remains functional under mechanical deformation. Additionally, it exhibits a strong and humidity-dependent electrical response, with peak performance at low humidity (20% relative humidity (RH)) and complete recovery of output after exposure to high humidity (70% RH), enabling potential applications as a self-powered humidity sensor. This study expands the range of two-dimensional (2D) materials for energy harvesting by demonstrating exf-AgInP2Se6 as a functional triboelectric material.

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