Publication details
X-ray structures of heteroleptic zinc(II) complexes involving combinations of O,O-dialkyldithiophosphato and bidentate N-donor ligands
| Authors | |
|---|---|
| Year of publication | 2014 |
| Type | Article in Periodical |
| Magazine / Source | Zeitschrift für Kristallographie - Crystalline Materials |
| MU Faculty or unit | |
| Citation | |
| Doi | http://dx.doi.org/10.1515/zkri-2014-1736 |
| Field | Inorganic chemistry |
| Keywords | 1 1-dithiolate dithiophosphate zinc(II) complexes crystal structure analysis X-ray diffraction |
| Attached files | |
| Description | The detailed X-ray structural elucidation of reaction products of a zinc(II) salt with O,O-dialkyldithiophosphate and nitrogen-containing heterocycles (N–N=1,10-phenanthroline (phen) or 2,2-bipyridine (bpy)) has been performed. Surprisingly, together with [Zn(S2P(OR)2)2(N–N)] compounds, also ionic-type complexes having the formula of [Zn(N–N)3](S2 P(OR)2)2 have been obtained using the same molar ratios of the reactants. The prepared complexes have been characterized by elemental analysis and single-crystal X-ray analysis. The crystallographic analysis showed that the bond lengths and bite angles of the prepared complexes are in good agreement with those of similar compounds. The crystal packing of described complexes is formed via pi–pi stacking interactions and/or C–H···S non-covalent contacts |