Publication details

Trigonal to tetrahedral transitions in Cu(I) six-membered inorganic true heterocycles

Authors

HORNÍ Michal BINAR Radim NEČAS Marek

Year of publication 2015
Type Conference abstract
MU Faculty or unit

Faculty of Science

Citation
Description In order to follow the influence of ligand substituents on the Cu(I) coordination geometry, a series of six-membered Cu(I) true heterocycles was prepared from reactions of Cu(PPh3)2NO3 with R2P(S)-NH-C(O)R’ {R’ = (CH2)3CH3, C6H5, C6H4F, C6H4Cl; R = Ph, PhO} ligands. The complexes were characterized by 31P NMR spectroscopy and single crystal X-ray diffraction.

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