Publication details
Syntéza a vlastnosti ferocenboronových derivátů vhodných k přípravě elektrochemicky aktivního umělého receptoru pro sacharidy
| Title in English | Synthesis of ferroceneboronic derivatives suitable for construction of electrochemically active synthetic receptor for saccharides |
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| Authors | |
| Year of publication | 2016 |
| Type | Article in Proceedings |
| Conference | Študentská vedecká konferencia PriF UK 2016 : Zborník recenzovaných príspevkov |
| MU Faculty or unit | |
| Citation | |
| Web | ŠVK UK - Zborník 2016 |
| Field | Biochemistry |
| Keywords | ferroceneboronic acid; electrochemistry; chemosensor; probe; detection of saccharides |
| Description | An electrochemically active synthetic receptor for saccharides consists of two connected parts - boronic acid is able to directly interact with an analyte and ferrocenyl residue provides electrochemical response on this binding event. These two parts joined together represents the probe - a receptor for the detection of saccharides. Throughout our way towards the saccharide-sensitive receptor, we synthesized three new imine derivatives of ferrocenylphenylboronic acid (FcPBA) and studied them by nuclear magnetic resonance, mass spectrometry, infrared spectroscopy and cyclic voltammetry. The results show some different behavior of the iminic ortho derivative due to intramolecular interactions of boronic functional group and iminic nitrogen atom. |