Publication details

[1-(1-Adamantylamino)ethylidene]oxonium methanesulfonate

Authors

VÍCHA Robert NEČAS Marek KOZUBKOVÁ Zuzana POTÁČEK Milan

Year of publication 2009
Type Article in Periodical
Magazine / Source Acta Crystallographica Section E: Structure Reports Online
MU Faculty or unit

Faculty of Science

Citation
Web http://journals.iucr.org/e/issues/2009/06/00/pk2161/index.html
Field Organic chemistry
Keywords MIT UROTROPIN-STRUKTUR; TETRAFLUOROBORATE; 1-ADAMANTANAMINE; ACETONITRILE; AGENTS
Description In the title salt, C12H20NO+center dot CH3SO3-, the [1-(1-adamantylamino)ethylidene]oxonium cations and methanesulfonate anions are linked into chains along the a axis via O-H center dot center dot center dot O and N-H center dot center dot center dot O hydrogen bonds. All non-H atoms of the acetamido group are essentially planar, with a maximum deviation of 0.0085 (12) angstrom. In comparison with related structures, the carbonyl C O bond is slightly elongated [1.249 (2) angstrom], whereas the amide C-N bond is shortened [1.292 (2) angstrom].

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