Publication details

Intermediate motions and dipolar couplings as studied by Lee-Goldburg cross-polarization NMR: Hartmann-Hahn matching profiles

Authors

COBO Marcio Fernando MALIŇÁKOVÁ Kateřina REICHERT Detlef SAALWÄCHTER Kay DEAZEVEDO Eduardo Ribeiro

Year of publication 2009
Type Article in Periodical
Magazine / Source Physical Chemistry Chemical Physics
MU Faculty or unit

Faculty of Science

Citation
Field Physical chemistry and theoretical chemistry
Keywords Lee-Goldburg cross-polarization; molecular motion in the intermediate regime; Hartmann-Hahn matching profiles; heteronuclear dipolar coupling
Description The use of simple Lee-Goldburg cross-polarization (LG-CP) NMR experiments for obtaining quantitative information of molecular motion in the intermediate regime is evaluated. In particular, measurement of Hartmann-Hahn matching profiles for the assessment of heteronuclear dipolar couplings as well as dynamics is introduced as an alternative to the more common analysis of build-up curves.

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