Publication details

Comparative study on fast classification of brick samples by combination of principal component analysis and linear discriminant analysis using stand-off and table-top laser induced breakdown spectroscopy

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Authors

VÍTKOVÁ Gabriela PROKEŠ Lubomír NOVOTNÝ Karel POŘÍZKA Pavel NOVOTNÝ Jan VŠIANSKÝ Dalibor ČELKO Ladislav KAISER Jozef

Year of publication 2014
Type Article in Periodical
Magazine / Source Spectrochimica Acta Part B: Atomic Spectroscopy
MU Faculty or unit

Faculty of Science

Citation
Doi http://dx.doi.org/10.1016/j.sab.2014.08.036
Field Analytic chemistry
Keywords Stand-off LIBS Classifcation; PCA; LDA; Cultural heritage
Description Focusing on historical aspect, during archaeological excavation or restoration works of buildings or different structures built from bricks it is important to determine, preferably insitu and in real-time, the locality of bricks origin. Fast classification of bricks on the base of Laser-Induced Breakdown Spectroscopy (LIBS) spectra is possible using multivariate statistical methods. Combination of principal component analysis (PCA) and linear discriminant analysis (LDA) was applied in this case. LIBS was used to classify altogether of 29 brick samples from 7 different localities. Realizing comparative study using two different LIBS setups – stand-off and table-top it is shown that stand-off LIBS has a big potential for archaeological in-field measurements.
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