Publication details

Protective double-layer coatings prepared by plasma enhanced chemical vapor deposition on tool steel

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Authors

MURESAN Mihai George CHARVÁTOVÁ CAMPBELL Anna ONDRAČKA Pavel BURŠÍKOVÁ Vilma PEŘINA Vratislav POLCAR Tomáš REUTER Stephan HAMMER Malte U. VALTR Miroslav ZAJÍČKOVÁ Lenka

Year of publication 2015
Type Article in Periodical
Magazine / Source Surface & coatings technology
MU Faculty or unit

Central European Institute of Technology

Citation
Web http://www.sciencedirect.com/science/article/pii/S0257897215003217
Doi http://dx.doi.org/10.1016/j.surfcoat.2015.04.002
Field Plasma physics
Keywords PECVD; DLC; Amorphous carbon; Hardness
Attached files
Description Hydrogenated diamond-like carbon films were prepared on high-speed steel substrates using low pressure radio-frequency capacitively coupled discharge (13.56 MHz) using methane mixed either with hydrogen or argon. A dc self-bias was induced by the rf discharge and accelerated the ions towards the substrates during the whole deposition process. Prior to the carbon film deposition and to improve the adhesion, the substrates were subject to plasma nitriding and coated with a silicon oxide layer using the same reactor. The deposited films were optically characterized (UV-IR) and by using a combination of Rutherford backscattering spectroscopy and elastic recoil detection the atomic composition was determined. The carbon films high hardness (similar to 18 GPa) was assessed from indentation tests. Adhesion tests revealed critical loads up to 13.6 N for the carbon films deposited on steel substrates using silicon oxide interlayer. Friction coefficient varied from 0.02 against diamond and 0.23 against steel counterpart. The results suggest that hard carbon films can be deposited on steel substrate using a silicon oxide intermediate layer deposited by the same plasma process with commercial potential. (C) 2015 Elsevier B.V. All rights reserved.
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