Publication details
On Thallium(III) Complexes with Tris(2-aminoethylamine) (tren)
| Authors | |
|---|---|
| Year of publication | 2006 |
| Type | Article in Periodical |
| Magazine / Source | Acta Universitatis Palackianae Olomucensis, Facultas Rerum Naturalium, Chemica |
| MU Faculty or unit | |
| Citation | |
| Field | Inorganic chemistry |
| Keywords | Thallium(III); polyamine complexes; equilibrium constants; tren |
| Description | The coordination compound [Tl(tren)2](NO3)3.H2O was prepared and characterized by elemental analysis and IR spectroscopy. The compound is well soluble in water and its aqueous solution is stable for several weeks. The protonation constants of complex were determined by acidimetric titration of the aqueous solution of complex at ionic strength I = 1.00 M (NaNO3) and temperature (25.0 +/- 0.1) degrees C. On the base of experimental facts, the possible structural formula of prepared compound has been proposed. |