Publication details

Belogubite, a New Mineral of the Chalcanthite Group from the Gaiskoe Deposit, South Urals, Russia

Authors

KASATKIN A. V. BRITVIN S. N. CHUKANOV N. V. ŠKODA Radek AGAKHANOV A. A. BELAKOVSKIY D. I.

Year of publication 2020
Type Article in Periodical
Magazine / Source Geology of Ore Deposits
MU Faculty or unit

Faculty of Science

Citation
Web https://link.springer.com/article/10.1134/S1075701520070065
Doi http://dx.doi.org/10.1134/S1075701520070065
Keywords belogubite; new mineral; chalcanthite group; Gaiskoe deposit; South Urals
Description Belogubite CuZn(SO4)(2) . 10H(2)O, a new mineral of the chalcanthite group, is found in the Gai (Gaiskoe) massive sulfide deposit, South Urals, Russia. This mineral forms aggregates of blue grains up to 1 mm. It is optically biaxial (-), n(p) = 1.512(2), n(m) = 1.525(2), n(g) = 1.531(2), 2V = 70(10)degrees. The chemical composition of the holotype sample is as follows (wt %): 1.12 MgO, 0.10 MnO, 3.15 FeO, 8.98 CuO, 18.02 ZnO, 32.49 SO3, and 36.75 H2O, total 100.61. The empirical formula is (Cu0.55Zn0.45)(sigma 1.00)(Zn0.64Fe0.22Mg0.14Mn0.01)(sigma 1.01)S1.99O7.98 . 10.02H(2)O. The crystal structure of belogubite is studied using the single crystal method, R = 0.016. The mineral is triclinic, P (1) over bar The unit cell parameters are: a = 6.2548(1), b = 10.6112(2), c = 6.0439(1) angstrom, alpha = 82.587(1), beta = 109.625(1), gamma = 104.848(1)degrees, V = 364.81(1) angstrom(3), and Z = 1. The strongest reflections of the powder XRD pattern [d(meas)., angstrom (I, %) (hkl) are: 5.73 (35) (100), 5.576 (47) (-110), 4.873 (100) (-111), 3.907 (31) (021), 3.719 (45) (0 -21), 3.229 (27) (111), 2.915 (25) (221), and 2.684 (26) (130).

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