Publication details
Regioselektivita a vliv chirální pomocné látky vázané na dipolu na enantioselektivitu 1,3-dipolární cykloadice
| Title in English | Regioselectivity and influence of chiral auxiliary bound on dipol upon enantioselectivity of 1,3-dipolar cycloaddition |
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| Authors | |
| Year of publication | 2001 |
| Type | Article in Proceedings |
| Conference | Sborník XXV. Konference organických chemiků |
| MU Faculty or unit | |
| Citation | |
| Field | Organic chemistry |
| Keywords | enantioselectivity; regioselectivity; chiral auxiliary; 1;3-dipolar cycloaddition; azomethine ylides |
| Description | Azomethine ylides based on phenanthridinium skeleton with bound chiral auxiliary were followed in 1,3-dipolar cycloaddition with dipolarophiles. Regioselectivity and enantioselectivity in the reaction was evaluated by COSY and HMBC NMR experiments as well as by HPLC with nonracemic sorbent on detector CD Jasco. |
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