Publication details
Reakce betainů kyseliny fluorofosforečné s protickými nukleofily.
| Title in English | Reactions of fluorophosphoric acid betaines with protic nucleophiles. |
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| Authors | |
| Year of publication | 2001 |
| Type | Article in Proceedings |
| Conference | 53. zjazd chemických spoločností. Sborník prispevkov 2. |
| MU Faculty or unit | |
| Citation | |
| Field | Inorganic chemistry |
| Keywords | Betaines; Fluorophosphoric acid; Protic nucleophiles; Amidofluorophosphates |
| Description | The hydrolysis and ammonolysis of fluorophosphoric acid betaines of the type B.PO2F was studied by 19F and 31P NMR spectroscopy. The main product of the hydrolysis is the 1,2-difluorodiphosphate, while the ammonolysis furnishes the amidofluoro- phosphate. Its condensation with betaine gives a hitherto unknown imido- 1,2-difluorodiphosphate, which is isoelectronic with above mentioned 1,2-difluorodiphosphate. |
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