Publication details
A regioselectivity of electrophilic attacks to 5-amino-3-thioxo-3H-1,2-dithiole-4-carboxylic acid functional derivatives. An elucidation of product structures
| Authors | |
|---|---|
| Year of publication | 2002 |
| Type | Article in Periodical |
| Magazine / Source | Heterocyclic Communications |
| MU Faculty or unit | |
| Citation | |
| Field | Organic chemistry |
| Keywords | regioselectivity; 1;2-dithiole; alkylation; acylation; 1;2-dithiolium; hydrogen bonding; X-ray structural analysis |
| Description | An acylation of 5-amino-3-thioxo-3H-1,2-dithiole-4-carboxylic acid functional derivatives led to the formation of N-acyl compound via S-acyl intermediate. On the other hand, alkylation occurred only at the sulfur atom of thioxo group. Structure elucidation of both types of products was done by IR, 1H, 13C NMR and X-ray structural analysis. |
| Related projects: |