Publication details
(N,N,N',N'',N''-Pentamethyldiethylenetriamine-[kappa]3N,N',N'')(trithiocyanurato-[kappa]2N,S)zinc(II)
| Authors | |
|---|---|
| Year of publication | 2007 |
| Type | Article in Periodical |
| Magazine / Source | Acta Crystallographica Section E: Structure Reports Online |
| MU Faculty or unit | |
| Citation | |
| Field | Inorganic chemistry |
| Keywords | Zinc(II); trithiocyanuric acid; structure; |
| Description | The structure of the title compound, [Zn(C9H23N3)(C3HN3S3)], consists of discrete molecules connected by N-H...S hydrogen bonds into centrosymmetric dimers. The ZnII atom is pentacoordinated in a deformed trigonal-bipyramidal geometry by three N atoms of a tridentate N,N,N',N'',N''-pentamethyldiethylenetriamine ligand, and one S and one N atoms of a trithiocyanurate dianion bonded as a bidentate ligand. The crystal structure is further stabilized by close contacts of the types C-H...S and C-H...N. |
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