Publication details
[1-(1-Adamantylamino)ethylidene]oxonium methanesulfonate
| Authors | |
|---|---|
| Year of publication | 2009 |
| Type | Article in Periodical |
| Magazine / Source | Acta Crystallographica Section E |
| MU Faculty or unit | |
| Citation | |
| Field | Organic chemistry |
| Keywords | UROTROPIN-STRUKTUR; TETRAFLUOROBORATE; 1-ADAMANTANAMINE; ACETONITRILE; AGENTS |
| Description | In the title salt, C12H20NO+center dot CH3SO3-, the [1-(1-adamantylamino)ethylidene]oxonium cations and methanesulfonate anions are linked into chains along the a axis via O-H center dot center dot center dot O and N-H center dot center dot center dot O hydrogen bonds. All non-H atoms of the acetamido group are essentially planar, with a maximum deviation of 0.0085 (12) angstrom. In comparison with related structures, the carbonyl C O bond is slightly elongated [1.249 (2) angstrom], whereas the amide C-N bond is shortened [1.292 (2) angstrom]. |