Publication details

Celsian from Ca-skarns associated with the Teshevo pluton, SW Bulgaria

Authors

VASSILEVA Rossitsa D. GEORGIEVA Sylvina GROZDEV Valentin GEORGIEVA Yana MILENKOV Georgi CEMPÍREK Jan

Year of publication 2025
Type Peer-reviewed scientific article
Magazine / Source SPISANIE NA BULGARSKOTO GEOLOGICHESKO DRUZHESTVO-REVIEW OF THE BULGARIAN GEOLOGICAL SOCIETY
MU Faculty or unit

Faculty of Science

Citation
web https://bgd.bg/REVIEW_BGS/REVIEW_BGD_2025_2/PDF/11_Vassileva_Rev_BGS_2025-2.pdf
Doi https://doi.org/10.52215/rev.bgs.2025.86.2.83
Keywords exoskarn; garnet; celsian; hyalophane
Description Celsian (BaAl2Si2O8) was identified for the first time in Bulgaria in Ca-skarns associated with the Teshevo granodiorite pluton. The rhythmically banded skarn zones formed along late-magmatic aplite/pegmatite dykes crosscuting both the granodiorite and the host marble. Skarn is composed mainly of garnet (grossular) and diopside. Celsian occurs as: i) euhedral crystals in garnet, commonly altered in variable extent to (Ba, K)-feldspar (hyalophane), or as ii) anhedral grains dispersed in the calc-silicate matrix. Electron-microprobe and LA-ICP-MS analyses show that BaO dominates the feldspar composition (37.9-40.3 wt%), whereas substitutions of K, Na, and Ca are minor. Strontium (up to 2483 ppm) is the most abundant trace element, whereas transition metals (Cu, Zn) and Ga were found in tens of ppm only; Y and Eu content are detectable but very low. The data indicate crystallization from Ba-rich hydrothermal fluids during late-magmatic to post-metasomatic stages. Celsian likely reflects Ba introduction by external fluids and records the evolution of metasomatic processes in skarns in the vicinity of the Teshevo pluton.

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