Metody přípravy katena-fluoropolyfosforečnanů.

• Title in English: Synthesis of katena-fluoropolyphosphates.
• Authors: SLUKA Radek; ČERNÍK Miloš
• Year of publication: 1999
• Type: Article in Proceedings
• Conference: 51. zjazd chemických spoločností. Zborník prispevkov 2.
• MU Faculty or unit: Faculty of Science
• Field: Inorganic chemistry
• Keywords: Fluoropolyphosphates; Synthesis; NMR spectroscopy; Solvolysis
• Description: A survey of new synthetic methods suitable for the preparation of katena-fluoropolyphosphate anions is presented. By contrast to earlier procedures, based on nucleophilic degradation of suitable substrates by fluoride anions and giving mostly a mixture of different fluoropolyphos- phates, the recent synthesis are highly specific and yields a distinct anion.In this respect, the most succesful are the solvolytic reactions of P-Cl or P-O-P bridge bonds with diphosphoryl tetrafluoride or trimet- hylsilyl difluorophosphate.

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