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Zobecněný princip eliminační voltametrie

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Title in English Generalized principle of elimination voltammetry


Year of publication 2003
Type Article in Periodical
Magazine / Source CHEMICKÉ LISTY
MU Faculty or unit

Faculty of Science

Field Electrochemistry
Keywords Eliminační voltametrie s lineárním scanem (EVLS);
Description For the elimination of chosen particular currents, elimination voltammetrie with linear scan (EVLS)employes the different dependences of voltammetric currents on scan rates. Elimination procedure is based on the simple principle, which can be generalized from the point of wiev of electrode polarization. The generalized principle was demonstrated on the case of elimination function mostly used. This elimination function eliminates charging and kinetic currents simultaneously and conserves the diffusion current. For various ratios of polarization rates coefficients of linear equations were calculated. According to values of coefficients in linear combinations and errors of these coefficients the choice of interval of chosen polarization rates is discussed.
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