Publication details
Substituted bicyclo[1.1.1]pentanes for molecular and supramolecular costruction set.
| Authors | |
|---|---|
| Year of publication | 2004 |
| Type | Article in Proceedings |
| Conference | Chemické listy, International Conference on Supramolecular Science & Technology, ICSS&T 2004 Congress Abstract Book |
| MU Faculty or unit | |
| Citation | |
| Field | Organic chemistry |
| Keywords | bicyclopentanes; staffanes |
| Description | We are introducing a new structural pattern 3 based on highly strained bicylo[1.1.1]pentane cage, which benefits from placing additional functionalities (FG) on its bridge positions. The new substituents are on two parallel bonds in positions 2 and 4, perpendicular to 1-3 axis of the cage. Such configuration enables interaction of the functionalities in an .equatorial. plane of the cage defined by its rotation around the 1-3 axis. If used in staffanes, these functionalities (polarizable, electron donating or accepting, ionizable, etc.) can propagate the interaction along the light of such molecular rod. |
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