Publication details

Orthogonal Photocleavage of a Monochromophoric Linker

Authors

KAMMARI Laxminarayana ŠOLOMEK Tomáš NGOY Bokolombe Pitchou HEGER Dominik KLÁN Petr

Year of publication 2010
Type Article in Periodical
Magazine / Source Journal of the American Chemical Society
MU Faculty or unit

Faculty of Science

Citation
Web http://pubs.acs.org/doi/abs/10.1021/ja1047736
Field Organic chemistry
Keywords Photochemistry; protecting groups.
Description The 4-acetyl-2-nitrobenzyl moiety, substituted in both benzylic and phenacyl positions with leaving groups, has been proposed as a monochromophoric photocleavable linker. The attached groups can be disconnected selectively and orthogonally upon irradiation.
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