Publication details

The synthesis and comparative characterization of three novel electroactive iminoboronates containing ferrocene

Authors

KONHEFR Martin LACINA Karel SKRUTKOVÁ LANGMAJEROVÁ Monika GLATZ Zdeněk SKLÁDAL Petr MAZAL Ctibor

Year of publication 2017
Type Article in Periodical
Magazine / Source Monatshefte für Chemie
MU Faculty or unit

Faculty of Science

Citation
Web https://link.springer.com/article/10.1007/s00706-017-2028-3
Doi http://dx.doi.org/10.1007/s00706-017-2028-3
Field Organic chemistry
Keywords Cyclic voltammetry;Donor-acceptor effect;Lewis acids;Metallocenes;Organometallic compounds;Schiff bases
Description Along our way towards the advanced saccharide-sensitive probes, three novel electroactive iminoboronate regioisomers of [(ferrocenylimino)methyl]phenylboronic acid have been synthesized. The ortho, meta, and para regioisomers were characterized structurally by NMR, MS, FT-IR, UV/Vis and their electrochemical behavior in aqueous solution was studied using cyclic voltammetry. The obtained results confirmed different behavior of the ortho isomer due to an interaction of boronic acid moiety with the proximate imine group of the iminoferrocenyl residue.
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