Publication details

Synthesis of Organotitanium(IV) Fluoride Phosphates and the Crystal Structure of [(C5Me4Et)TiF(m-F){m-O2P(OSiMe3)2}]2

Authors

PEVEC Andrej DEMŠAR Alojz PINKAS Jiří NEČAS Marek

Year of publication 2012
Type Article in Periodical
Magazine / Source Acta Chimica Slovenica
MU Faculty or unit

Central European Institute of Technology

Citation
Web http://acta.chem-soc.si/59/59-1-203.pdf
Field Inorganic chemistry
Keywords titanium; fluoride; phosphate; X-ray structure
Attached files
Description The complexes [(C5Me4R)TiF(m-F){m-O2P(OSiMe3)2}]2 [R = Me (1), Et (2)] were prepared from [(C5Me4R)TiF3]2, (R = Me, Et) and OP(OSiMe3)3. The molecular structure of 2 has been determined by single-crystal X-ray diffraction analysis. An eight-membered Ti2O4P2 metallacycle bridged by two fluorine ligands between two titanium centers is observed.
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