Informace o publikaci
Synthesis of Organotitanium(IV) Fluoride Phosphates and the Crystal Structure of [(C5Me4Et)TiF(m-F){m-O2P(OSiMe3)2}]2
| Autoři | |
|---|---|
| Rok publikování | 2012 |
| Druh | Článek v odborném periodiku |
| Časopis / Zdroj | Acta Chimica Slovenica |
| Fakulta / Pracoviště MU | |
| Citace | |
| www | http://acta.chem-soc.si/59/59-1-203.pdf |
| Obor | Anorganická chemie |
| Klíčová slova | titanium; fluoride; phosphate; X-ray structure |
| Přiložené soubory | |
| Popis | The complexes [(C5Me4R)TiF(m-F){m-O2P(OSiMe3)2}]2 [R = Me (1), Et (2)] were prepared from [(C5Me4R)TiF3]2, (R = Me, Et) and OP(OSiMe3)3. The molecular structure of 2 has been determined by single-crystal X-ray diffraction analysis. An eight-membered Ti2O4P2 metallacycle bridged by two fluorine ligands between two titanium centers is observed. |
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