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Redistribution of incompatible elements during hydrothermal alteration of pegmatite from the Djurkovo Pb-Zn deposit, Central Rhodopes

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GEORGIEVA Sylvina VASSILEVA Rossitsa D. GROZDEV Valentin MILENKOV Georgi CEMPÍREK Jan ŠKODA Radek STEFANOVA Elitsa

Rok publikování 2023
Druh Článek v odborném periodiku
Časopis / Zdroj Review of the Bulgarian Geological Society
Fakulta / Pracoviště MU

Přírodovědecká fakulta

Citace
www https://bgd.bg/REVIEW_BGS/REVIEW_BGD_2023_3/PDF/06_Georgieva-S_Rev_BGS_2023-3.pdf
Doi http://dx.doi.org/10.52215/rev.bgs.2023.84.3.35
Klíčová slova pegmatites; (REE plus Y; U; Th)-(Nb; Ta; Ti) oxide minerals; ishikawaite; fergusonite; fersmite
Popis Mineralogical and geochemical study was done on weakly deformed, relatively thin pegmatites that in-truded the marbles of the Rhodope metamorphic complex in the Djurkovo Pb-Zn deposit, Central Rhodopes. The pegmatites consist mainly of K-feldspar and quartz and contain minor garnet; the pegmatites lack clear zonation ex-cept for the preferable crystallization of the garnet in the central parts. The main accessory minerals are ishikawaite, zircon, monazite-(Ce), apatite, and titanite. The textural relationships indicate later hydrothermal alteration of pegma-tites which led to the formation of albite, epidote, sericite, chlorite, carbonate, quartz and leucoxene. The (REE+Y, ACT, Nb, Ta, Ti)-bearing pegmatite minerals (oxides, silicates and phosphates) are partly leached and/or replaced by secondary ones. The newly-formed phases precipitated as anhedral grains along fractures and dissolved zones onto/ or close to the primary minerals due to the limited mobility of the incompatible elements in fluids conditioned by pH, ligand activity and temperature.

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