Informace o publikaci
Applied Thermodynamics: Grain Boundary Segregation
| Autoři | |
|---|---|
| Rok publikování | 2014 |
| Druh | Článek v odborném periodiku |
| Časopis / Zdroj | Entropy |
| Fakulta / Pracoviště MU | |
| Citace | |
| www | http://www.mdpi.com/1099-4300/16/3/1462 |
| Doi | https://doi.org/10.3390/e16031462 |
| Obor | Fyzika pevných látek a magnetismus |
| Klíčová slova | APPLIED TENSILE-STRESS; LOW-ALLOY STEEL; INTERFACIAL SEGREGATION; SOLUTE INTERACTION; ALPHA-IRON; PHOSPHORUS; ANISOTROPY; EMBRITTLEMENT; ENTHALPY |
| Popis | Chemical composition of interfaces-free surfaces and grain boundaries-is generally described by the Langmuir-McLean segregation isotherm controlled by Gibbs energy of segregation. Various components of the Gibbs energy of segregation, the standard and the excess ones as well as other thermodynamic state functions-enthalpy, entropy and volume-of interfacial segregation are derived and their physical meaning is elucidated. The importance of the thermodynamic state functions of grain boundary segregation, their dependence on volume solid solubility, mutual solute-solute interaction and pressure effect in ferrous alloys is demonstrated |
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