Informace o publikaci
Synthesis and Supramoleculer properties of water soluble Bambusuril derivative
| Autoři | |
|---|---|
| Rok publikování | 2015 |
| Druh | Konferenční abstrakty |
| Citace | |
| Popis | Supramoleculer host that operates in “real life” environments are of great interest for biological and industrial chemist. Water is one of major environment in real life. Development of such a Supramoleculer host that serves as anion receptors in pure water is a challenging task for chemists.1 Previously only a few effective neutral anion receptors functioning in water are known. Herein we report an approach for the synthesis of a unique receptor bambusuril derivative 5 that shows strong associations toward several inorganic anions including iodide and perchlorate up to 107 M-1 in water.2 NMR titration method was applied for the determination of association constants of all investigated anions; furthermore the associations of halides with bambusuril 5 were also examined by ITC. We also demonstrate that bambusuril 5 can be used for the qualitative and quantitative detection of anions at micromolar concentrations in pure water at pH 7.1.3 |