Informace o publikaci
N-Cyclohexylcyclohexanaminium chloride
| Autoři | |
|---|---|
| Rok publikování | 2011 |
| Druh | Článek v odborném periodiku |
| Časopis / Zdroj | Acta Crystallographica Section E: Structure Reports Online |
| Fakulta / Pracoviště MU | |
| Citace | |
| www | https://doi.org/10.1107/S1600536811000857 |
| Doi | http://dx.doi.org/10.1107/S1600536811000857 |
| Klíčová slova | single-crystal X-ray study; T = 120 K; mean (C–C) = 0.003 angstrom; R factor = 0.025; wR factor = 0.057; data-to-parameter ratio = 9.0 |
| Popis | In the title salt, C12H24N+center dot Cl-, both cyclohexyl rings adopt chair conformations and the NH2 unit is situated in the equatorial position with respect to the rings in the cation. The large C-N-C bond angle [117.99 (14)degrees] in the cation is a result of linking two bulky cyclohexyl rings to the N atom. The aminium H atoms are involved in intermolecular N-H center dot center dot center dot Cl hydrogen bonds, forming an infinite zigzag chain parallel to the c axis. The crystal studied was a racemic twin with a twin fraction of 0.28 18). |