Informace o publikaci
Molecular Aluminophosphonate: Model Compound for the Isoelectronic Double-Six-Ring (D6R) Secondary Building Unit of Zeolites
| Autoři | |
|---|---|
| Rok publikování | 1998 |
| Druh | Článek v odborném periodiku |
| Časopis / Zdroj | Angew. Chem. Int. Ed. Engl. |
| Fakulta / Pracoviště MU | |
| Citace | |
| Obor | Anorganická chemie |
| Klíčová slova | aluminum; phosphonates; structure elucidation; zeolite analogues |
| Popis | The reaction of tert-butylphosphonic acid with equimolar quantities of AlMe3 in THF/n-hexane yields a mixture of [MeAlO3PtBu]6 (1) and [MeAlO3PtBu]4 (2). The molecular structure of 1 resembles the D6R building units found in aluminophosphates. The central core of the Al6O18P6 polyhedron can be described as a cylindrical drum. By tailoring the alkyl groups on aluminum and phosphorus, it is possible to generate bigger building units of aluminophosphate molecular sieves. |