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Self-assembled layers of nucleic acid components at Hg and Au electrodes.

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HASOŇ Stanislav VETTERL Vladimír

Rok publikování 2000
Druh Článek ve sborníku
Konference Book of Abstracts, J.Heyrovský Memorial Symposium, Praha
Fakulta / Pracoviště MU

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Citace
Obor Biofyzika
Klíčová slova self-assembled layers; adsorption; two-dimensional condesation; cytidine; deoxycytidine;
Popis The kinetics of structural changes in cytidine and deoxycytidine adlayers on the mercury electrode were investigated by means of current and capacitance transients using the potential step technique. By means of j-t transients we studied the processes taking place at the beginning of the growth or dissolution of physical condensed and highly ordered adlayers. On the other site the C-t transients revealed changes taking place within physical condensed cytidine adlayers at longer times. The experimental curves were analysed by comparison with several models based on the nucleation and growth in combination with a parallel Lanqmuir-type desorption process.
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