Informace o publikaci
[1-(1-Adamantylamino)ethylidene]oxonium methanesulfonate
| Autoři | |
|---|---|
| Rok publikování | 2009 |
| Druh | Článek v odborném periodiku |
| Časopis / Zdroj | Acta Crystallographica Section E: Structure Reports Online |
| Fakulta / Pracoviště MU | |
| Citace | |
| www | http://journals.iucr.org/e/issues/2009/06/00/pk2161/index.html |
| Obor | Organická chemie |
| Klíčová slova | MIT UROTROPIN-STRUKTUR; TETRAFLUOROBORATE; 1-ADAMANTANAMINE; ACETONITRILE; AGENTS |
| Popis | In the title salt, C12H20NO+center dot CH3SO3-, the [1-(1-adamantylamino)ethylidene]oxonium cations and methanesulfonate anions are linked into chains along the a axis via O-H center dot center dot center dot O and N-H center dot center dot center dot O hydrogen bonds. All non-H atoms of the acetamido group are essentially planar, with a maximum deviation of 0.0085 (12) angstrom. In comparison with related structures, the carbonyl C O bond is slightly elongated [1.249 (2) angstrom], whereas the amide C-N bond is shortened [1.292 (2) angstrom]. |