Informace o publikaci
Dimethylamino Gallatrane: Solution and Gas Phase Behavior
| Autoři | |
|---|---|
| Rok publikování | 1996 |
| Druh | Článek v odborném periodiku |
| Časopis / Zdroj | Polyhedron |
| Fakulta / Pracoviště MU | |
| Citace | |
| Obor | Anorganická chemie |
| Klíčová slova | tautomerism; gallium; atranes |
| Popis | The gallatrane Ga(OCH2CH2)(3)N (1) forms a dimethylamine adduct, which exists in solutions in two tautomeric forms : a tricyclic cage, Me(2)NHGa(OCH2CH2)(3)N, and an open-cage bicyclic species Me(2)NGa(OCH2CH2)(2)NCH2CH2OH, which were identified by H-1, C-13 and Ga-71 NMR spectroscopy. The mass spectrum of the adduct revealed a homologous series of oligomers of 1(n), where n = 1, 2, 3 and 4. |